Chaudhari, R. V. ; Seayad, A. ; Jayasree, S. (2001) Kinetic modeling of homogeneous catalytic processes Catalysis Today, 66 (2-4). pp. 371-380. ISSN 0920-5861
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S09205...
Related URL: http://dx.doi.org/10.1016/S0920-5861(00)00633-7
Abstract
Homogeneous catalysis by soluble metal complexes is gaining considerable attention due to their unique applications and features like high activity and selectivity. In this paper, a brief review of kinetic modeling in homogeneous catalysis has been presented. Approaches using empirical as well as molecular level rate models have been discussed. Special features relevant to asymmetric catalysis and multiple rate controlling steps have also been addressed. A case study on kinetics of carbonylation of 1-(4-iso-butylphenyl)ethanol using a homogeneous palladium catalyst has been discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Homogeneous Catalysis; Kinetics; Rate Equation; Hydrogenation; Hydroformylation; Carbonylation; 1-(4-iso-butylphenyl)ethanol; Ibuprofen |
| ID Code: | 7652 |
| Deposited On: | 25 Oct 2010 10:55 |
| Last Modified: | 28 May 2011 11:51 |
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