Divekar, S. S. ; Deshpande, R. M. ; Chaudhari, R. V. (1993) Kinetics of hydroformylation of 1-decene using homogeneous HRh(CO)(PPh3)3 catalyst: a molecular level approach Catalysis Letters, 21 (1-2). pp. 191-200. ISSN 1011-372X
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Official URL: http://www.springerlink.com/content/kx85350jp28p82...
Related URL: http://dx.doi.org/10.1007/BF00767385
Abstract
The kinetics of hydroformylation of 1-decene using homogenous HRh(CO)(PPh3)3 catalyst has been reported in the temperature range of 50-70 °C. The effect of catalyst,P H 2,P CO, and 1-decene concentration on the rate of hydroformylation has been studied. Based on the analysis of initial rate data, a rate equation has been proposed and kinetic parameters evaluated. The activation energy was found to be 11.76 kcal/mol. A molecular level approach to kinetic modelling has also been illustrated. The rate equation derived assuming oxidative addition of H2 as a rate determining step, has been found to represent the data satisfactorily. The rate parameters for the mechanistic model have been evaluated for the data at 60 °C.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer-Verlag. |
| Keywords: | Hydroformylation; Rhodium Complexes; Alkene Functionalization |
| ID Code: | 7580 |
| Deposited On: | 25 Oct 2010 11:06 |
| Last Modified: | 30 May 2011 04:43 |
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