Dhavale, Dilip D. ; Desai, Vijaya N. ; Saha, Nabendu N. ; Tilekar, Jayant N. (2002) Chiron approaches to polyhydroxylated piperidines: promising glycosidase inhibitors ARKIVOC: Online Journal of Organic Chemistry, 7 . pp. 91-105. ISSN 1424-6376
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Official URL: http://www.arkat-usa.org/get-file/20167/
Abstract
New chiron approaches towards the syntheses of polyhydroxylated piperidine analogues are described. The methodologies involve 1,3-addition of methyl magnesium bromide and silyl ketene acetal to D-glucose derived nitrone, intramolecular Michael addition to D-glucose derived á,â-unsaturated ester and double reductive amination of 5-keto aldose as key steps.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Arkat-USA, Inc. |
| Keywords: | Alkaloids; Piperidines; Nitrone; Reductive Amination; Conjugate Addition; Enzyme Inhibitors |
| ID Code: | 75352 |
| Deposited On: | 22 Dec 2011 13:10 |
| Last Modified: | 22 Dec 2011 13:10 |
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