Karche, Navnath P. ; Jachak, Santosh M. ; Dhavale, Dilip D. (2003) Synthesis of griseolic acid analogues: regioselective a-facial [1,2]-migration in the rhodium acetate catalyzed reaction of D-glucose derived α-diazo-β-keto ester Journal of Organic Chemistry, 68 (11). pp. 4531-4534. ISSN 0022-3263
Full text not available from this repository.
Official URL: http://pubs.acs.org/doi/abs/10.1021/jo026858j
Related URL: http://dx.doi.org/10.1021/jo026858j
Abstract
This paper describes an efficient route for the synthesis of known and novel griseolic acid analogues 1d and 1e, respectively. The key intermediate dioxabicyclo derivative 6, with the required stereochemical orientation at C6, was obtained by rhodium acetate catalyzed reaction of D-glucose derived α-diazo-β-keto ester 5 in a novel high-yielding methodology.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 75348 |
| Deposited On: | 22 Dec 2011 13:10 |
| Last Modified: | 22 Dec 2011 13:10 |
Repository Staff Only: item control page
