Crystallization kinetics of Zr65Ag5Cu12.5Ni10Al 7.5 glassy powders produced by ball milling of pre-alloyed ingots

Prashanth, K. G. ; Scudino, S. ; Surreddi, K. B. ; Sakaliyska, M. ; Murty, B. S. ; Eckert, J. (2009) Crystallization kinetics of Zr65Ag5Cu12.5Ni10Al 7.5 glassy powders produced by ball milling of pre-alloyed ingots Materials Science and Engineering A, 513-514 . pp. 279-285. ISSN 0921-5093

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.msea.2009.01.075

Abstract

Ball milling was employed to produce Zr65Ag5Cu12.5Ni10Al 7.5 glassy powder from pre-alloyed mixtures of crystalline intermetallic compounds. Differential scanning calorimetry (DSC) in isochronal as well as in isothermal modes was used to study the thermal stability and the crystallization kinetics of the glassy powder. The activation energy for crystallization was calculated using isothermal and isochronal DSC data as well as from viscosity measurements, which lead to values of the activation energy ranging between 298 and 314 kJ/mol. Johnson-Mehl-Avrami analysis shows that the transformation is a diffusion controlled three-dimensional process and the crystallization proceeds with increasing nucleation rate at annealing temperatures within the super-cooled liquid region. To test the effectiveness of the glassy powder as reinforcement in Al-based metal matrix composites, bulk specimens consisting of pure Al powder blended with 50 vol.% of Zr65Ag5Cu12.5Ni10Al 7.5 glassy powder were synthesized by powder metallurgy. Room temperature compression tests reveal that the strength increases from 155 MPa for pure Al to 235 MPa for the composite with 50 vol.% of glass reinforcement.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Metallic Glasses; Powder Metallurgy; Kinetics; Calorimetry
ID Code:73879
Deposited On:08 Dec 2011 03:56
Last Modified:08 Dec 2011 03:56

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