Dimerization and the initial pressure dependence of the viscosity of polar gases

Singh, Yashwant ; Deb, S. K. ; Barua, A. K. (1967) Dimerization and the initial pressure dependence of the viscosity of polar gases The Journal of Chemical Physics, 46 (10). pp. 4036-4040. ISSN 0021-9606

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Official URL: http://jcp.aip.org/resource/1/jcpsa6/v46/i10/p4036...

Related URL: http://dx.doi.org/10.1063/1.1840483

Abstract

The contributions of bound and metastably bound molecules to the second virial coefficient of polar gases have been calculated by assuming equal probability for all the relative orientations of the interacting dipoles. The results have been utilized to explain the initial pressure dependence of the viscosity of polar gases. The results obtained for steam and ammonia are quite satisfactory.

Item Type:Article
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ID Code:73162
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