On the inclusion of triplet potentials into the born-green theory of fluids

Singh, Y. ; Ram, J. (1972) On the inclusion of triplet potentials into the born-green theory of fluids Journal of the Physical Society of Japan, 33 . pp. 585-592. ISSN 0031-9015

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Official URL: http://jpsj.ipap.jp/link?JPSJ/33/585

Related URL: http://dx.doi.org/10.1143/JPSJ.33.585

Abstract

The equation of the Born-Green theory has been rederived by including the triplet potentials. It has been found that the resulting equation can be written in terms of effective pair potential defined as, φe(i, j)=φ(i, j)-kTX(i, j), where X(i, j) represents a sub-set of line irreducible diagrams defined by Casanova et al. (Mol. Phys. 18 (1970) 589). The nonadditive contributions to the third and fourth virial coefficients as obtained from the extended Born-Green theory have been discussed briefly.

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