Christy Rani Grace, R. ; Anil Kumar, (1994) Construction of energy level diagram of oriented benzene using connectivity information obtained by modified Z-COSY experiment Proceedings of the Indian Academy of Sciences - Chemical Sciences, 106 (9). pp. 1463-1469. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/j_archive/chemsci/106/9/1463-...
Abstract
Experiments involving selective perturbation of a transition yield information about the directly connected transitions, which in turn yield information for deriving the parameters of the spin Hamiltonian of oriented molecules. Problems involved with selective perturbation are removed by the use of a two-dimensional experiment, namely, the modified Z-COSY-experiment, The use of this experiment is demonstrated for obtaining the connectivity information and for determining the parameters of the spin Hamiltonian of oriented benzene, a strongly coupled six-spin system.
Item Type: | Article |
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Source: | Copyright of this article belongs to Indian Academy of Sciences. |
Keywords: | Assignment of Spectra; Connected Transitions; NMR of Oriented Molecules; Two Dimensional (2-D) NMR |
ID Code: | 72807 |
Deposited On: | 02 Jul 2012 12:53 |
Last Modified: | 18 May 2016 17:54 |
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