Copper(II) complexes of a novel ligand 4,5-dicyanoimidazole: structural and magnetic studies

Prasad, B. L. V. ; Sato, Hirohiko ; Enoki, Toshiaki ; Cohen, Shmuel ; Radhakrishnan, T. P. (1999) Copper(II) complexes of a novel ligand 4,5-dicyanoimidazole: structural and magnetic studies Journal of the Chemical Society Dalton Transactions (1). pp. 25-30. ISSN 1472-7773

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Official URL: http://xlink.rsc.org/?doi=a805623d

Related URL: http://dx.doi.org/10.1039/A805623D

Abstract

The potential use of 4,5-dicyanoimidazolate ion (DCI-) as a bridging ligand for magnetically interesting co-ordination polymers has been explored. New CuII-bipy complexes containing DCI- were prepared and characterised; crystal structure analysis revealed DCI- co-ordinated CuII in one of the complexes. The ESR and magnetic susceptibility studies showed that the compounds are nearly Curie paramagnetic or weakly antiferromagnetic. A polymeric structure is proposed for one of the complexes.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:72560
Deposited On:29 Nov 2011 04:13
Last Modified:29 Nov 2011 04:13

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