Jayanty, S. ; Radhakrishnan, T. P. (2001) Solid-state charge transfer promoted by an anchoring agent: a two-component analogue of kofler's ternary complex Chemistry of Materials, 13 (6). pp. 2072-2077. ISSN 0897-4756
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Official URL: http://pubs.acs.org/doi/abs/10.1021/cm000884l
Related URL: http://dx.doi.org/10.1021/cm000884l
Abstract
Charge-transfer complex formation between the push-pull zwitterionic molecule 7,7-bis(piperazino)-8,8-dicyanoquinodimethane and picric acid is observed in the solid state. The critical role of proton transfer and intermolecular H bonding in facilitating the charge-transfer interaction is established through control experiments and single-crystal X-ray investigation of the complex. The details of the π -π interaction are analyzed using computed atomic charges.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 72519 |
| Deposited On: | 29 Nov 2011 04:28 |
| Last Modified: | 29 Nov 2011 04:28 |
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