Singh, Anil K. (1986) Extrinsic circular dichroic effects in retinoates Journal of the Chemical Society, Perkin Transactions 2, 2 (5). pp. 635-636. ISSN 0300-9580
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Official URL: http://pubs.rsc.org/en/content/articlelanding/1986...
Related URL: http://dx.doi.org/10.1039/P29860000635
Abstract
(−)-1-Phenylethyl retinoate shows a Cotton effect with c.d. bands at 360, 245, and 215 nm, whereas (+)-octan-2-yl retinoate has no such band in the 220-450 nm region. This can be explained either in terms of a dipole-dipole interaction between the phenyl and retinylidene moieties or in terms of the dissymmetric environment of the polyene. The results are pertinent to the origin of c.d. in rhodopsins.
Item Type: | Article |
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Source: | Copyright of this article belongs to Royal Society of Chemistry. |
ID Code: | 72106 |
Deposited On: | 28 Nov 2011 06:03 |
Last Modified: | 28 Nov 2011 06:03 |
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