Ravikumar, K. S. ; Chandrasekaran, Srinivasan (1996) Reaction of diisopropoxytitanium(III) tetrahydroborate with selected organic compounds containing representative functional groups Journal of Organic Chemistry, 61 (3). pp. 826-830. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo951313t
Related URL: http://dx.doi.org/10.1021/jo951313t
Abstract
Diisopropoxytitanium(III) tetrahydroborate, (iPrO)2TiBH4, generated in situ in dichloromethane from diisopropoxytitanium dichloride and benzyltriethylammonium borohydride in a 1:2 ratio selectively reduces aldehydes, ketones, acid chlorides, carboxylic acids, and N-Boc-protected amino acids to the corresponding alcohols in excellent yield under very mild reaction conditions (-78 to 25 °C).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 7184 |
| Deposited On: | 25 Oct 2010 12:20 |
| Last Modified: | 03 Feb 2011 06:11 |
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