Lalitha, S. ; Chandrasekhar, Jayaraman ; Mehta, Goverdhan (1990) Cage geometry controlled hyperstability in bridgehead olefins Tetrahedron Letters, 31 (29). pp. 4219-4222. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/S0040-4039(00)97586-5
Abstract
MM2 calculations indicate that roofed polyquinane ring systems containing trans double bonds are hyperstable. The stability results from repulsions at the rim of the cylindrical cage in the hydrogenated forms.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 7170 |
| Deposited On: | 25 Oct 2010 12:24 |
| Last Modified: | 05 Feb 2011 08:36 |
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