Swaminathan, S. ; Srinivasan, K. G. ; Venkataramani, P. S. (1970) Rearrangements of bicyclic-δ-hydroxy-α,β-enones—IV : base catalysed rearrangements of some bicyclic-α-substituted-δ-hydroxy-α,β-enones Tetrahedron, 26 (5). pp. 1453-1461. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)92974-6
Abstract
The hydroxy enones 5a, 5b, 5c, 4d, 4a and 4b rearrange when treated with aqueous alkali to the diones 6a, 6b, 8 and 13 and acids 9 and 12 respectively. The diones 2 and 6a are also formed by thermal rearrangement of enones 1a and 5a.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
ID Code: | 70773 |
Deposited On: | 21 Nov 2011 05:25 |
Last Modified: | 21 Nov 2011 05:25 |
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