Anionic oxycope rearrangements in acetylenic spiro systems

Ravikumar, V. T. ; Rajagopalan, K. ; Swaminathan, S. (1985) Anionic oxycope rearrangements in acetylenic spiro systems Tetrahedron Letters, 26 (49). pp. 6137-6138. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)95107-4

Abstract

The anionic oxy-Cope rearrangement of the acetylenic carbinol 3 furnishes the tricyclic diketone 5; substitution at the key position furnishes only the bicyclic 1,3-bridged dione 6.

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