Narayanan, K. V. ; Selvarajan, R. ; Swaminathan, S. (1968) Stereochemistry of hindered benzophenones: synthesis and resolution of 3-carboxymethyl-2,2',4,4',6,6'-hexamethyl-3'-nitrobenzophenone Journal of the Chemical Society C Organic, 1968 . pp. 540-543. ISSN 0022-4952
Full text not available from this repository.
Official URL: http://pubs.rsc.org/en/content/articlelanding/1968...
Related URL: http://dx.doi.org/10.1039/J39680000540
Abstract
3-Bromo-2,2',4,4',6,6'-hexamethyl-3'-nitro-, 2,2'4,5',6-pentamethyl-3-nitro-, 3-bromo-2,2',4,6-tetramethyl-5'-nitro-, and 2,2',4,4',6,6'-hexamethyl-3-methoxycarbonylmethyl-3'-nitro-benzophenone were prepared by Friedel-Crafts acylation. The last compound was hydrolysed to 3-carboxymethyl-2,2',4,4',6,6'-hexamethyl-3'-nitrobenzophenone, which was resolved by way of the brucine salt; this demonstrates for the first time the existence of optical isomerism in suitably substituted benzophenones because of steric interactions between the o- and o'-substituents.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 70748 |
| Deposited On: | 21 Nov 2011 05:27 |
| Last Modified: | 21 Nov 2011 05:27 |
Repository Staff Only: item control page
