Mahajan, Sudhakar S. ; Idage, Bhaskar B. ; Sarawade, Bhimrao D. ; Chavan, Nakayu N. ; Sivaram, Swaminathan (1991) Oxidative polymerization of 2,6-dimethylphenol by copper(II)chloride-amine complexes: effect of amines on polymerization activity Journal of Macromolecular Science: Part A - Chemistry, 28 (Suppl.1). pp. 7-13. ISSN 1060-1325
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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0022233...
Related URL: http://dx.doi.org/10.1080/00222339108054377
Abstract
2, 6-Dimethylphenol (2,6-DMP) undergoes oxidative polymerization with CuCl2.2H2O-aliphatic amine complexes in a 70:30(v/v) o-dichlorobenzene-ethanol solvent. Unlike pyridine, polymerization occurs even in the absence of added base. Apart from basicity, factors such as steric effects and nature of ligand coordination to Cu(II) have profound effect on catalyst reactivity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Group. |
| ID Code: | 70036 |
| Deposited On: | 18 Nov 2011 12:53 |
| Last Modified: | 18 Nov 2011 12:53 |
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