Mathur, D. ; Badrinathan, C. ; Marathe, V. R. (1989) Trends in the energies of cation and anion states of alkan-1-ols Oms (Organic Mass Spectrometry), 24 (8). pp. 625-631. ISSN 0030-493X
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/oms.121...
Related URL: http://dx.doi.org/10.1002/oms.1210240819
Abstract
We report results of a systematic investigation of the energies of positive-ion and negative-ion states in alkan-1-ol molecules CnH2n+1 OH (n = 1-5) in low-energy electron impact experiments using a beam of nearly mono-energetic electrons. The measurements have been conducted in a crossed electron-beam/molecular-beam apparatus wherein positive ions are detected using a quadrupole mass spectrometer whereas unstable negative ions are observed as resonance structures in the electron transmission function. Theoretical calculations of anion and cation energies have been carried out using the semi-empirical HAM/3 technique.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons. |
| ID Code: | 69041 |
| Deposited On: | 08 Nov 2011 04:21 |
| Last Modified: | 08 Nov 2011 04:21 |
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