Pal, Chandan Kumar ; Chattopadhyay, Surajit ; Sinha, Chittaranjan ; Chakravorty, Animesh (1992) Synthesis and structure of a thioazobenzene palladacycle: oxygen insertion into the Pd---C bond by m-chloroperbenzoic acid Journal of Organometallic Chemistry, 439 (1). pp. 91-99. ISSN 0022-328X
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002232...
Related URL: http://dx.doi.org/10.1016/0022-328X(92)80056-4
Abstract
The reaction of p-tolyl-o'-(2-chloroethylthio)azobenzene (L1H) with Na2PdCl4 affords the complex PdL1Cl, the structure of which has been determined by X-ray crystallography. The azobenzene ligand acts in the tridentate (C,N,S) fashion and the fourth coordination position is occupied by the chloride ion. In the lattice, the PdL1Cl molecules are present as loose dimers of parallel Pd(C,N,S)Cl units, the Pd...Pd distance being 3.357(2)Å.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 6866 |
| Deposited On: | 26 Oct 2010 05:19 |
| Last Modified: | 31 Jan 2011 08:27 |
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