Dayal, R. ; Ramachandra Rao, D. ; Venkateswarlu, Putcha (1979) Electron paramagnetic resonance study of Mn2+-doped iron, cobalt, and nickel perchlorate hexahydrates Journal of Magnetic Resonance - Series A, 36 (1). pp. 99-111. ISSN 1064-1858
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0022-2364(79)90219-1
Abstract
Mn2+-doped Fe(CIO4)2·6H2O, Co(ClO4)2·6H2O, and Ni(ClO4)2·6H2O have been studied by EPR from room temperature to liquid nitrogen temperature. Mn2+ replaces the metal ions at sites of trigonal symmetry. The EPR lines are broad and the D parameters are small; thus, there is considerable overlap in the spectra. The spectra are nearly axially symmetric. The temperature variation study shows phase transitions at 237 ± 5, 154.5 ± 6.5, and 223 ± 5 K in iron, cobalt, and nickel perchlorate hexahydrates, respectively.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
ID Code: | 68637 |
Deposited On: | 02 Nov 2011 10:56 |
Last Modified: | 02 Nov 2011 10:56 |
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