Dayal, R. ; Ramachandra Rao, D. ; Venkateswarlu, Putcha (1979) Electron paramagentic resonance and phase transitions in Mn2+ doped Cd(ClO4)2·6H2O The Journal of Chemical Physics, 70 (5). 2487_1-2487_4. ISSN 0021-9606
Full text not available from this repository.
Official URL: http://jcp.aip.org/resource/1/jcpsa6/v70/i5/p2487_...
Related URL: http://dx.doi.org/10.1063/1.437711
Abstract
An electron paramagnetic resonance study of Mn2+ doped in Cd(ClO4)2·6H2O has been made from 328 K to liquid nitrogen temperature. The site symmetry of Cd2+ is trigonal with a water octahedron distorted parallel to the crystallographic c axis. Mn2+ substitutes for Cd2+ and exhibits a characteristic 30-line hyperfine spectrum at room temperature (298 K) for the magnetic field H along the c axis. The D parameter is small and therefore there is considerable overlapping of lines in the spectrum. The spectrum is axially symmetric. On lowering the temperature, phase transitions are found to occur at 272± 1 and 115.5± 1 K.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Institute of Physics. |
| ID Code: | 68579 |
| Deposited On: | 02 Nov 2011 10:56 |
| Last Modified: | 02 Nov 2011 10:56 |
Repository Staff Only: item control page
