Mizushima, Masataka ; Venkateswarlu, Putcha (1953) The possible microwave absorption in the molecules belonging to the point groups D2d Ξ Vd and Td The Journal of Chemical Physics, 21 (4). pp. 705-709. ISSN 0021-9606
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Official URL: http://jcp.aip.org/resource/1/jcpsa6/v21/i4/p705_s...
Related URL: http://dx.doi.org/10.1063/1.1698994
Abstract
It is shown that pure rotational absorption in the molecules belonging to the point group D2d Ξ Vd is possible if the molecule is in the excited, preferably lowest, doubly degenerate vibrational state. The approximate positions of these microwave absorption lines, as calculated from the B value obtained from the infrared data, are given in the case of allene. It is also shown that the pure rotational absorption is possible in the molecules belonging to the point group Td if they are in the excited triply degenerate (F2) vibrational states. The matrix element of dipole moment corresponding to our transition is about the same as that of the overtone vibrational bands, in both cases.
Item Type: | Article |
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Source: | Copyright of this article belongs to American Institute of Physics. |
ID Code: | 68553 |
Deposited On: | 02 Nov 2011 10:41 |
Last Modified: | 02 Nov 2011 10:41 |
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