MCM-41 anchored cinchona alkaloid for catalytic asymmetric dihydroxylation of olefins: a clean protocol for chiral diols using molecular oxygen

Choudary, Boyapati M. ; Chowdari, Naidu S. ; Jyothi, Karangula ; Kantam, Mannepalli L. (2002) MCM-41 anchored cinchona alkaloid for catalytic asymmetric dihydroxylation of olefins: a clean protocol for chiral diols using molecular oxygen Catalysis Letters, 82 (1-2). pp. 99-102. ISSN 1011-372X

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Official URL: http://www.springerlink.com/content/j030t8873548q4...

Related URL: http://dx.doi.org/10.1023/A:1020504511203

Abstract

MCM-41 anchored 1,4-bis(9-O-quininyl)phthalazine (MCM-(QN)2PHAL)-OsO4, is prepared for the first time and used in the heterogeneous asymmetric dihydroxylation of olefins to afford diols with good to excellent enantiomeric excesses in the presence of N-methylmorpholine N-oxide, K3Fe(CN)6 or molecular oxygen as cooxidants.

Item Type:Article
Source:Copyright of this article belongs to Springer-Verlag.
Keywords:Asymmetric Synthesis; Dihydroxylation; Immobilization; Olefins; Oxygen; Osmium
ID Code:6850
Deposited On:26 Oct 2010 05:22
Last Modified:28 May 2011 09:05

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