Lakshmi Kantam, M. ; Laha, Soumi ; Yadav, Jagjit ; Likhar, Pravin R. ; Sreedhar, B. ; Choudary, B. M. (2007) Asymmetric hydrosilylation of prochiral ketones catalyzed by nanocrystalline copper(II) oxide Advanced Synthesis & Catalysis, 349 (10). pp. 1797-1802. ISSN 1615-4150
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/adsc.20...
Related URL: http://dx.doi.org/10.1002/adsc.200600481
Abstract
Asymmetric hydrosilylation of aryl alkyl ketones to afford chiral secondary alcohols with good yields and excellent enantioselectivity is realized by using nanocrystalline copper(II) oxide and BINAP in the presence of organosilanes as the stoichiometric reducing agents.
Item Type: | Article |
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Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
Keywords: | Asymmetric Hydrosilylation; Heterogeneous Catalysis; Nanocrystalline Copper(II) Oxide; Reduction; Secondary Alcohols |
ID Code: | 6819 |
Deposited On: | 26 Oct 2010 05:27 |
Last Modified: | 28 May 2011 08:08 |
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