Synthesis of cyanomaclurin-I: synthesis of some model compounds

Bhatia, G. D. ; Mukerjee, S. K. ; Seshadri, T. R. (1966) Synthesis of cyanomaclurin-I: synthesis of some model compounds Tetrahedron, 22 (Suppl. 7). pp. 139-143. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4020(01)99102-1

Abstract

Based on NMR evidence cyanomaclurin is considered to have a chromanochroman (cyanomacluran) skeleton. In order to provide synthetic support three model compounds without the 13-hydroxyl group have been prepared. These are 3-methoxy, 1,3-dimethoxy and 3,9-dimethoxy cyanomaclurans made from corresponding 2'-hydroxy flavanones. Their properties and the readiness with which the final chroman ring closure takes place, support the structure of cyanomaclurin.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:68139
Deposited On:02 Nov 2011 11:27
Last Modified:02 Nov 2011 11:27

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