Scope of isoflavone synthesis using 2'-benzyloxychalkone epoxides

Bhrara, S. C. ; Jain, A. C. ; Seshadri, T. R. (1965) Scope of isoflavone synthesis using 2'-benzyloxychalkone epoxides Tetrahedron, 21 (5). pp. 963-967. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0040-4020(65)80034-5

Abstract

Boron trifluoride-etherate reacts with 2'-benzyloxychalkone epoxides to give mainly dihydroflavonols if ring B is unsubstituted, but isoflavones are formed by rearrangement if methoxy groups are present in positions 4 or 3 and 4. These factors limit the applicability of isoflavone synthesis using chalkone epoxides.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:68136
Deposited On:02 Nov 2011 11:18
Last Modified:02 Nov 2011 11:18

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