Choudary, B. M. ; Lakshmi Kantam, M. ; Rahman, Ateeq ; Venkat Reddy, Ch. ; Koteswara Rao, K. (2001) The first example of activation of molecular oxygen by nickel in Ni-Al hydrotalcite: a novel protocol for the selective oxidation of alcohols Angewandte Chemie International Edition, 40 (4). pp. 763-766. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/1521-37...
Related URL: http://dx.doi.org/10.1002/1521-3773(20010216)40:4<763::AID-ANIE7630>3.0.CO;2-T
Abstract
NiO in association with aluminum oxide has been identified by temperature-programmed reduction as the active species in the Ni–Al hydrotalcite catalyst that oxidizes α-ketols as well as benzylic and allylic alcohols to their corresponding carbonyl compounds in oxygen in quantitative yields under mild reaction conditions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Alcohols; Hydrotalcites; Oxidation; Oxygen; Reduction |
| ID Code: | 6813 |
| Deposited On: | 26 Oct 2010 05:28 |
| Last Modified: | 28 May 2011 09:12 |
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