Time resolved fluorescence spectroscopy of quinine sulphate, quinidine and 6-methoxyquinoline: pH dependence

Pant, Debi ; Tripathi, H. B. ; Pant, D. D. (1992) Time resolved fluorescence spectroscopy of quinine sulphate, quinidine and 6-methoxyquinoline: pH dependence Journal of Luminescence, 51 (4). pp. 223-230. ISSN 0022-2313

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002223...

Related URL: http://dx.doi.org/10.1016/0022-2313(92)90057-G

Abstract

The excited state dynamics of quinine sulphate (QS), quinidine (Qd) and 6-methoxyquinoline (6MQ) has been studied as a function of pH in steady state and nanosecond time resolved fluorescence experiments. The solvent relaxation process is a dominant process for all the molecules studied, irrespective of pH. Moreover, 6MQ undergoes a proton transfer reaction in the excited state at pH 7 whereas QS and Qd do not exhibit excited state protonation.

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