Effect of anion coordination upon radiationless transitions of the uranyl ion

Joshi, G. C. ; Dangwal, G. C. ; Pant, D.D. ; Tripathi, H. B. (1983) Effect of anion coordination upon radiationless transitions of the uranyl ion Chemical Physics Letters, 96 (2). pp. 167-170. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...

Related URL: http://dx.doi.org/10.1016/0009-2614(83)80485-0

Abstract

At 80 K, where the deactivation processes in uranyl luminescence in solutions are temperature independent, the radiationless transition rate depends upon the presence of H2O in the first coordination sphere of the uranyl ion, UO22+. It is found that such radiationless transitions are due to a photophysical intramolecular process.

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