Effect of aggregation on the radiative (T1 → S0) and nonradiative (T10 and S1 ↝ T1) transitions in xanthene dyes

Joshi, N. B. ; Pant, D. D. (1976) Effect of aggregation on the radiative (T1 → S0) and nonradiative (T10 and S1 ↝ T1) transitions in xanthene dyes Journal of Luminescence, 14 (1). pp. 1-8. ISSN 0022-2313

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002223...

Related URL: http://dx.doi.org/10.1016/0022-2313(76)90033-8

Abstract

The measurement of triplet decay time (Τp) and the relative yields of phosphorescence to fluorescence (φpf) have been made in solutions of xanthene dyes. The value of φpf increases while that of Τp decreases as the concentration of the solution is increased. The rate constants kp, kqp and kis have been estimated. It is found that the values of kqp and kis increase while that of kp remains substantially constant for the entire range of concentration. The deuterium solvent effect is observed in Τp and φp.

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Deposited On:02 Nov 2011 09:50
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