New photoluminescent CuIN4 chromophores. Stabilisation of copper(I) by unconjugated diimines

Chowdhury, Shubhamoy ; Patra, Goutam K. ; Drew, Michael G. B. ; Chattopadhyay, Nitin ; Datta, Dipankar (2000) New photoluminescent CuIN4 chromophores. Stabilisation of copper(I) by unconjugated diimines Journal of the Chemical Society, Dalton Transactions (3). pp. 235-237. ISSN 1472-7773

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2000...

Related URL: http://dx.doi.org/10.1039/A909224B

Abstract

Two new photoluminescent homoleptic distorted tetrahedral CuIN4 chromophores with CuII/I potentials of 0.66-0.81 V vs. SCE are isolated by using two unconjugated diimines (2:1 condensates of R1R2C=O and ethylenediamine; R1 = Ph, R2 = H; R1 = R2 = Ph) as ligands.

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