Probe-induced self-aggregation of γ-cyclodextrin: formation of extended nanotubular suprastructure

Das, Paramita ; Mallick, Arabinda ; Sarkar, Deboleena ; Chattopadhyay, Nitin (2008) Probe-induced self-aggregation of γ-cyclodextrin: formation of extended nanotubular suprastructure The Journal of Physical Chemistry C, 112 (26). pp. 9600-9603. ISSN 1932-7447

Full text not available from this repository.

Official URL: http://pubs.acs.org/doi/abs/10.1021/jp801951j

Related URL: http://dx.doi.org/10.1021/jp801951j

Abstract

Time-resolved fluorescence anisotropy decay analysis, dynamic light scattering (DLS), and transmission electron microscopy (TEM) techniques have been exploited to substantiate and characterize the formation of a substrate-anchored γ-cyclodextrin nanotubular suprastructure in aqueous medium, the diameter and the length of the entity being ~250 nm and a few micrometers, respectively. Similar aggregation is not observed with α- and β-cyclodextrins. Dimensions of the substrate and the cyclodextrin cavity have been ascribed to control the formation of the substrate-induced elongated aggregates. The report projects a simple way to design nanotubes of variable dimensions with a proper choice of the anchoring probe and the cyclodextrin.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:67452
Deposited On:31 Oct 2011 05:10
Last Modified:31 Oct 2011 05:10

Repository Staff Only: item control page