Choudary, Boyapati Manoranjan ; Chowdari, Naidu Sreenivasa ; Kantam, Mannepalli Lakshmi (1999) Enantioselective Michael addition reactions catalyzed by a new heterobimetallic asymmetric complex Journal of Molecular Catalysis A: Chemical, 142 (3). pp. 389-392. ISSN 1381-1169
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Official URL: http://dx.doi.org//10.1016/S1381-1169(98)00325-2
Related URL: http://dx.doi.org/10.1016/S1381-1169(98)00325-2
Abstract
A heterobimetallic catalyst obtained by reaction of LiAlH4 with aminodiol derived from natural (+)-tartaric acid promotes asymmetric Michael addition of malonic esters, thiophenols and nitro alkanes to cyclic and acyclic enones with excellent yields albeit low enantiomeric excess.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Asymmetric Michael Addition; Heterobimetallic Catalyst; Enones; Malonates |
| ID Code: | 6744 |
| Deposited On: | 22 Oct 2010 06:24 |
| Last Modified: | 22 Oct 2010 06:24 |
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