The shape and extended fine structure of the manganese K X-ray absorption discontinuity in its oxides

Apte, M. Y. ; Mande, C. (1980) The shape and extended fine structure of the manganese K X-ray absorption discontinuity in its oxides Journal of Physics and Chemistry of Solids, 41 (4). pp. 307-312. ISSN 0022-3697

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0022-3697(80)90201-2

Abstract

The shape and extended fine structure of the manganese K absorption discontinuity have been studied in the pure metal and in its four oxides. viz. MnO, Mn3O4, Mn2O3 ad MnO2 using a bent crystal Cauchois type spectrograph of 40cm diameter. The shape of the main discontinuity for the oxides is discussed on the basis of molecular orbital theory. Our results show a complimentarity between the absorption spectra and the emission spectra obtained earlier by Tsutsumi et al. for some of these oxides. The extended X-ray absorption fine structure (EXAFS) is discussed in the light of the recent proposed by Lytle et al.

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