Aime, J. P. ; Ramakrishnan, S. ; Chance, R. R. ; Kim, M. W. (1990) The effect of substituent groups on polymer conformation in good solvent: polyoctene and polydecene Journal de Physique, 51 (10). pp. 963-975. ISSN 0302-0738
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Official URL: http://jphys.journaldephysique.org/index.php?optio...
Related URL: http://dx.doi.org/10.1051/jphys:019900051010096300
Abstract
The influence of the size of the side group is a key parameter for understanding the local rigidity of soluble conjugated polymers. We report an additional experimental proof with a light scattering study upon very simple saturated polymers with different side group extension : polyoctene and polydecene. The results show an unambiguous relation between the statistical length and the size of the side group. We also show that the magnitude of the statistical length is not the relevant parameter for describing the optical properties of the conjugated polymers in solution.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to EDP Sciences. |
| Keywords: | Light Scattering; Macromolecular Configurations; Polymer Solutions |
| ID Code: | 67254 |
| Deposited On: | 29 Oct 2011 12:01 |
| Last Modified: | 29 Oct 2011 12:01 |
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