Chemistry of chromium bis-acetylide complexes

López-Hernández, A. ; Venkatesan, K. ; Schmalle, H. W. ; Berke, Heinz (2009) Chemistry of chromium bis-acetylide complexes Monatshefte fur Chemie / Chemical Monthly, 140 (7). pp. 845-857. ISSN 0026-9247

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Official URL: http://www.springerlink.com/content/82913665v77418...

Related URL: http://dx.doi.org/10.1007/s00706-008-0094-2

Abstract

Stable paramagnetic Cr(II) and Cr(III) bis(alkynyl) complexes of the type [trans(RC≡ C)2Cr(dmpe)2] n+ (R = Ph, SiMe3, SiEt3, C≡C-SiMe3 n=0, 1) were prepared and characterised by NMR, cyclic voltammetry, EPR, magnetic measurements, and X-ray single-crystal diffraction studies.

Item Type:Article
Source:Copyright of this article belongs to Springer.
Keywords:Alkynes; Magnetic Properties; Molecular Wires; Oligomers; X-ray Structure Determination
ID Code:66673
Deposited On:27 Oct 2011 04:17
Last Modified:27 Oct 2011 04:17

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