Padmanabhan, Kaillathe ; Döpp, Dietrich ; Venkatesan, Kailasam ; Ramamurthy, Vaidyanathan (1986) Solid-state photochemistry of nitro compounds: structure-reactivity correlations Journal of Chemical Society, Perkin Transactions 2, 2 (6). pp. 897-906. ISSN 0300-9580
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1986...
Related URL: http://dx.doi.org/10.1039/P29860000897
Abstract
The molecular structures of 1-t-butyl-3,5-dimethyl-2,4,6-trinitrobenzene, 1-t-butyl-3,4,5-trimethyl-2,6-dinitrobenzene, and 1-t-butyl-4-acetyl-3,5-dimethyl-2,6-dinitrobenzene have been determined by single-crystal X-ray analyses with a view to establishing a structure-reactivity relationship in the photochemical intramolecular hydrogen-abstraction process in the solid state. The reactivity of these aromatic nitro compounds in the solid state has been rationalized in terms of relevant intramolecular geometrical parameters as well as intermolecular packing considerations.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 66596 |
| Deposited On: | 27 Oct 2011 04:11 |
| Last Modified: | 27 Oct 2011 04:11 |
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