Synthesis of large generation poly(propyl ether imine) (PETIM) dendrimers

Jayamurugan, Govindasamy ; Jayaraman, Narayanaswamy (2006) Synthesis of large generation poly(propyl ether imine) (PETIM) dendrimers Tetrahedron, 62 (41). pp. 9582-9588. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tet.2006.07.094

Abstract

Large generation poly(propyl ether imine) (PETIM) dendrimers are synthesized in iterative synthetic cycles of two reductions and two Michael addition reactions. Dendrimers up to sixth generation, containing up to 128 peripheral functionalities, are synthesized. Growth of the PETIM dendrimers, possessing a tertiary amine as the branch juncture and an ether as the linker component, is assessed systematically by routine spectroscopic methods. The peripheries of these dendrimers possess either alcohols, amines, carboxylic acids, esters, or nitriles, thereby opening up possibilities for varied studies involving PETIM dendrimers.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Dendrimers; Iterative Synthesis; Michael Addition; Raney Cobalt
ID Code:65976
Deposited On:20 Oct 2011 07:12
Last Modified:20 Oct 2011 07:12

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