Herm, Zoey R. ; Krishna, Rajamani ; Long, Jeffrey R. (2012) CO2/CH4, CH4/H2 and CO2/CH4/H2 separations at high pressures using Mg2(dobdc) Microporous and Mesoporous Materials, 151 . pp. 481-487. ISSN 1387-1811
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.micromeso.2011.09.004
Abstract
High-pressure separations of binary and ternary mixtures of CO2, CH4, and H2 are relevant to carbon dioxide capture as well as hydrogen and natural gas purification. Metal-organic frameworks represent a class of porous materials that could be used to accomplish these separations, and Mg2(dobdc) (dobdc4- = 1,4-dioxido-2,5-benzenedicarboxylate), also sometimes referred to as Mg-MOF-74 or CPO-27-Mg, is an especially lightweight metal-organic framework with a high concentration of coordinatively-unsaturated metal sites decorating its interior surfaces. High pressure CH4 adsorption isotherms presented here, together with CO2 and H2 adsorption behavior, are analyzed using the ideal adsorbed solution theory to model CO2/CH4, CH4/H2, and CO2/CH4/H2 mixture separations using Mg2(dobdc). The selectivities, working capacities and breakthrough performances for these three mixtures are reported, and Mg2(dobdc) is shown to outperform zeolite 13χ in each scenario.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Metal-Organic Framework; Carbon Capture; Mg2(dobdc); Hydrogen Purification; Natural Gas Purification |
| ID Code: | 65334 |
| Deposited On: | 17 Oct 2011 03:31 |
| Last Modified: | 18 Jun 2012 11:44 |
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