Suzuki-Miyaura cross-coupling and ring-closing metathesis: a strategic combination for the synthesis of cyclophane derivatives

Kotha, Sambasivarao ; Mandal, Kalyaneswar (2006) Suzuki-Miyaura cross-coupling and ring-closing metathesis: a strategic combination for the synthesis of cyclophane derivatives European Journal of Organic Chemistry, 2006 (23). pp. 5387-5393. ISSN 1434-193X

Full text not available from this repository.

Official URL: http://onlinelibrary.wiley.com/doi/10.1002/ejoc.20...

Related URL: http://dx.doi.org/10.1002/ejoc.200600549

Abstract

The synthesis of cyclophane derivatives through a sequence involving Suzuki-Miyaura cross-coupling between α, α'-dibromo-m-xylene and arylboronic acid derivatives, alkenylation and ring-closing metathesis has been achieved. One of the cyclophanes was obtained by tandem isomerization and metathesis. Significant magnetic anisotropic effects on the intra-annular hydrogen atoms were observed.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons.
Keywords:Cyclophanes; Isomerization; Olefin Metathesis; Palladium; Ruthenium; Suzuki-Miyaura Cross-coupling
ID Code:65199
Deposited On:15 Oct 2011 11:44
Last Modified:15 Oct 2011 11:44

Repository Staff Only: item control page