Kotha, Sambasivarao ; Mandal, Kalyaneswar (2006) Suzuki-Miyaura cross-coupling and ring-closing metathesis: a strategic combination for the synthesis of cyclophane derivatives European Journal of Organic Chemistry, 2006 (23). pp. 5387-5393. ISSN 1434-193X
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/ejoc.20...
Related URL: http://dx.doi.org/10.1002/ejoc.200600549
Abstract
The synthesis of cyclophane derivatives through a sequence involving Suzuki-Miyaura cross-coupling between α, α'-dibromo-m-xylene and arylboronic acid derivatives, alkenylation and ring-closing metathesis has been achieved. One of the cyclophanes was obtained by tandem isomerization and metathesis. Significant magnetic anisotropic effects on the intra-annular hydrogen atoms were observed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Cyclophanes; Isomerization; Olefin Metathesis; Palladium; Ruthenium; Suzuki-Miyaura Cross-coupling |
| ID Code: | 65199 |
| Deposited On: | 15 Oct 2011 11:44 |
| Last Modified: | 15 Oct 2011 11:44 |
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