New synthetic approach to a [1.1. 6] metapara cyclophane derivative via Suzuki-Miyaura cross-coupling and ring-closing metathesis

Kotha, Sambasivarao ; Mandal, Kalyaneswar ; Arora, Kapildev K. ; Pedireddi, V. R. (2005) New synthetic approach to a [1.1. 6] metapara cyclophane derivative via Suzuki-Miyaura cross-coupling and ring-closing metathesis Advanced Synthesis & Catalysis, 374 (9). pp. 1215-1218. ISSN 1615-4150

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/adsc.20...

Related URL: http://dx.doi.org/10.1002/adsc.200404373

Abstract

The synthesis of a [1.1.6] metapara cyclophane derivative, 1,5(1,4),3(1,3)-tribenzenacycloundecaphan-8-ene-6,11-dione, has been achieved via the Suzuki-Miyaura cross-coupling of α, α'-dibromo-m-xylene with an arylboronic acid derivative followed by an allylation and ring-closing metathesis reaction sequence.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons.
Keywords:Cyclophanes; Olefin Metathesis; Palladium; Ruthenium; Suzuki-Miyaura Cross-coupling
ID Code:65192
Deposited On:15 Oct 2011 11:42
Last Modified:15 Oct 2011 11:42

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