Ethyl 6-acetylamino-6,7-dihydro-5H-dibenzo[a,c]cycloheptene-6-carboxylate

Damodharan, Lakshminarasimhan ; Shamaladevi, Nagarajarao ; Pattabhi, Vasantha ; Behera, Manoranjan ; Kotha, Sambasivarao (2002) Ethyl 6-acetylamino-6,7-dihydro-5H-dibenzo[a,c]cycloheptene-6-carboxylate Acta Crystallographica Section C, 58 (5). o266-o267. ISSN 0108-2701

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Official URL: http://onlinelibrary.wiley.com/doi/10.1107/S010827...

Related URL: http://dx.doi.org/10.1107/S0108270102004687

Abstract

The title compound, C20H21NO3, is a derivative of Aib (α-aminoisobutyric acid) and is cyclized at the Cα position by bi-phenyl rings. The seven-membered ring possesses C2 symmetry. The Cα cyclization causes the backbone to assume a helical conformation in the crystal structure. The packing of the mol-ecules is stabilized by intermolecular C-H···O, C-H···π and N-H···O hydrogen bonds.

Item Type:Article
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ID Code:65188
Deposited On:15 Oct 2011 11:39
Last Modified:15 Oct 2011 11:39

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