Synthesis of a new fluorescent macrocyclic α-amino acid derivative via tandem cross-enyne/ring-closing metathesis cascade catalyzed by ruthenium based catalysts

Kotha, Sambasivarao ; Bansal, Deepti ; Singh, Kuldeep ; Banerjee, Subhasree (2011) Synthesis of a new fluorescent macrocyclic α-amino acid derivative via tandem cross-enyne/ring-closing metathesis cascade catalyzed by ruthenium based catalysts Journal of Organometallic Chemistry, 696 (9). pp. 1856-1860. ISSN 0022-328X

Full text not available from this repository.

Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.jorganchem.2011.02.019

Abstract

A simple methodology to a unique macrocyclic α-amino acid (AAA) derivative involving three step synthetic sequence has been reported. In addition, various ruthenium based catalysts were studied to enhance the selectivity of the desired macrocyclic AAA derivative 6. The fluorescence behavior of these AAA derivatives 5 and 6 indicate their potential applications in biological sciences as biomarkers, ion sensors and peptidomimetics.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:65161
Deposited On:15 Oct 2011 11:48
Last Modified:15 Oct 2011 11:48

Repository Staff Only: item control page