Rodolakis, F. ; Hansmann, P. ; Rueff, J.-P. ; Toschi, A. ; Haverkort, M. W. ; Sangiovanni, G. ; Tanaka, A. ; Saha-Dasgupta, T. ; Andersen, O. K. ; Held, K. ; Sikora, M. ; Alliot, I. ; Itié, J. P. ; Baudelet, F. ; Wzietek, P. ; Metcalf, P. ; Marsi, M. (2010) Inequivalent routes across the Mott transition in V2O3 explored by X-ray absorption Physical Review Letters, 104 (4). 047401_1-047401_4. ISSN 0031-9007
Full text not available from this repository.
Official URL: http://prl.aps.org/abstract/PRL/v104/i4/e047401
Related URL: http://dx.doi.org/10.1103/PhysRevLett.104.047401
Abstract
The changes in the electronic structure of V2O3 across the metal-insulator transition induced by temperature, doping, and pressure are identified using high resolution x-ray absorption spectroscopy at the V pre-K edge. Contrary to what has been taken for granted so far, the metallic phase reached under pressure is shown to differ from the one obtained by changing doping or temperature. Using a novel computational scheme, we relate this effect to the role and occupancy of the a1g orbitals. This finding unveils the inequivalence of different routes across the Mott transition in V2O3.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to The American Physical Society. |
| ID Code: | 65073 |
| Deposited On: | 15 Oct 2011 12:02 |
| Last Modified: | 15 Oct 2011 12:02 |
Repository Staff Only: item control page
