Umapathy, S. ; McQuillan, A. J. ; Hester, R. E. (1990) An in situ resonance Raman and infrared spectroscopic study of hexacyanoferrate (II) ion adsorbed to aqueous colloidal TiO2 Chemical Physics Letters, 170 (1). pp. 128-132. ISSN 0009-2614
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0009-2614(90)87103-X
Abstract
Resonance Raman and Fourier-transform infrared spectroscopies have been used to study the charge- transfer reactions of adsorbed hexacyanoferrate(ii) on colloidal TiO2. The spectroscopic results are analysed in terms of the molecular symmetry imposed by the various possible orientations of hexacyanoferrate(ii) on the TiO2 surface. It is concluded that the hexacyanoferrate(ii) is adsorbed onto colloidal TiO2 via either one or Two CN groups.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 64990 |
| Deposited On: | 15 Oct 2011 12:29 |
| Last Modified: | 15 Oct 2011 12:29 |
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