Electrical conduction in nanocomposites of copper in silicate glasses

Maity, A. K. ; Nath, D. ; Chakravorty, D. (1996) Electrical conduction in nanocomposites of copper in silicate glasses Journal of Physics: Condensed Matter, 8 (31). pp. 5717-5723. ISSN 0953-8984

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Official URL: http://iopscience.iop.org/0953-8984/8/31/005

Related URL: http://dx.doi.org/10.1088/0953-8984/8/31/005

Abstract

Nanocomposites of metallic copper in a silica-based glass have been prepared by the hot compaction of ion-exchanged and reduced glass powders. The diameter of copper particles ranges from 5.7 to 9.2 nm. The specimens exhibit a semiconducting behaviour in the temperature range 80-333 K with an unusually low activation energy of the order of 3.0 meV. This result appears to be consistent with a quantum size effect.

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