Roy, Mithun ; Bhowmick, Tuhin ; Ramakumar, Suryanarayanarao ; Nethaji, Munirathinam ; Chakravarty, Akhil R. (2008) Double-strand DNA cleavage from photodecarboxylation of (μ-oxo)diiron(III) L-histidine complex in visible light Dalton Transactions . pp. 3542-3545. ISSN 1477-9226
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Official URL: http://www.rsc.org/Publishing/Journals/DT/article....
Related URL: http://dx.doi.org/10.1039/b802533a
Abstract
The oxo-bridged diiron(III) complex [{Fe(L-his)(dpq)}2(μ-O)]2+ having L-histidine (L-his) and dipyrido[3,2-d:2,3-f]quinoxaline (dpq) bound to Fe(III) exemplifies an iron-based model photonuclease that shows visible light-induced DNA double-strand cleavage in a photodecarboxylation pathway and models iron-bleomycin activity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 6462 |
| Deposited On: | 20 Oct 2010 10:05 |
| Last Modified: | 24 May 2011 10:38 |
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