Heterolytic cleavage of homoallylic alcohols—I: fragmentation of 6-hydroxycamphene derivatives

Yadav, J. S. ; Patil, Dilip G. ; Krishna, R. R. ; Chawla, H. P. S. ; Dev, Sukh (1982) Heterolytic cleavage of homoallylic alcohols—I: fragmentation of 6-hydroxycamphene derivatives Tetrahedron, 38 (7). pp. 1003-1007. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0040-4020(82)85079-5

Abstract

Heterolytic fragmentation of homoallylic alcohols incorporated in a bicyclo[2,2,1]heptane system with electrophilic reagents or that of the corresponding epoxides with acids, is described. A short route, via this fragmentation, to synthon 25, potentially useful in the syntheses of cis-jasamone and prostanoids, is reported.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:64533
Deposited On:08 Oct 2011 12:28
Last Modified:12 Jul 2012 11:41

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