Meenakumari, Shanmugam ; Chakravarty, Akhil R. (1993) Covalent attachment of two important dicopper(II) systems in a one-dimensional polymeric chain: an x-ray structure of [Cu2(en)2(OH)2·Cu2(O2CMe)4](PF6)2·0.5EtOH]α showing the shortest Cu...Cu Distance in the tetraacetato core Polyhedron, 12 (14). pp. 1825-1827. ISSN 0277-5387
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S02775...
Related URL: http://dx.doi.org/10.1016/S0277-5387(00)84620-3
Abstract
Reaction of Cu2(O2CMe)4(H2O)2 with 1,2-diaminoethane(en) in ethanol, followed by the addition of NH4PF6, led to the formation of a covalently linked 1D polymeric copper(II) title complex showing alternating [Cu2(en)2(OH)22+] and [Cu2(O2CMe)4] units in the chain and the shortest CuCu separation of 2.558(2) Å in the tetraacetato core.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 6426 |
| Deposited On: | 20 Oct 2010 10:25 |
| Last Modified: | 27 May 2011 05:21 |
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