Mandal, Sisir K. ; Chakravarty, Akhil R. (1992) Arene ruthenium complexes of N,N'- and N,O-donor schiff base ligands: an X-ray structure of [(η6-p-cymene) RuCl(C5,H4N-2-CH=NC6H4-p-Me)Cl·C6H6·H2O Polyhedron, 11 (7). pp. 823-827. ISSN 0277-5387
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Official URL: http://dx.doi.org//10.1016/S0277-5387(00)86017-9
Related URL: http://dx.doi.org/10.1016/S0277-5387(00)86017-9
Abstract
Arene ruthenium(II) Schiff base complexes of formulations [(η -p-cymene)RuCl(C5H4N-2-CH=NC6H4-p-X)](ClO4) (1) and [(η6-p-cymene)RuCl(O-o-C6H4CH=NC6H4-p-X)] (2) (X = H, Me, OMe, NO2, Cl) were prepared by reacting [(η6-p-cymene)RuCl2]2 with corresponding pyridine-2-carboxaldimines and sodium salts of salicylaldimines in dry THF, respectively. Complex 1 is isolated as a perchlorate salt. The molecular structure of [(η6-p-cymene)RuCl(C5H4 N-2-CH=NC6H4-p-Me)]Cl·C6H6·H2O has been determined by X-ray crystallography. The complex contains an η6-p-cymene group, a chloride and a bidentate chelating Schiff base ligand.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 6408 |
| Deposited On: | 20 Oct 2010 10:28 |
| Last Modified: | 27 May 2011 05:23 |
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